pI-Trap Original

pI-Trap

The pI-trap utilizes a series of vessels with a capillary passing through each vessel. Part of the capillary in each vessel is replaced by a semipermeable membrane. The vessels contain buffer solutions with different pH values, so that a pH gradient is effectively established inside the capillary...

Biomotif pI-Trap instrument features:

  • Fast (<1 h) separation in ESI-friendly solution
  • Easy fraction collection, up to 30 fractions
  • On-line clean-up of sample
  • Fractionation of raw samples, e.g., intact blood plasma or serum
  • Couple on-line to any API-Mass Spectrometer
  • Orthogonal dimension to RP-LC-MS in Deep-Proteomics
  • Large capacity (up to 100 μg) for enrichment of low abundance molecules
  • Minimal sample losses
  • Rapid isolation of a defined pI region
  • Accurate pI determination of your molecule
  • Push-button operation

The pI-trap utilizes a series of vessels with a capillary passing through each vessel. Part of the capillary in each vessel is replaced by a semipermeable membrane. The vessels contain buffer solutions with different pH values, so that a pH gradient is effectively established inside the capillary. The buffer solution in each vessel has an electrical contact with a voltage divider connected to a high-voltage power supply, which established electrical field along the capillary. When a sample (a mixture of peptides or proteins) is injected in the capillary, the presence of the electrical field and the pH gradient n separates these molecules according to their isoelectric points (pI).

Heart of the device is the pI-Cell, based on proprietary microfluidic technology. Take it as an electrical column, capturing charged molecules according to their isoelectric point.

https://en.wikipedia.org/wiki/Isoelectric_focusing

Please contact us for demo or instrument evaluation!

Publications

  1. Chingin, K.; Astorga-Wells, J.; Pirmoradian Najafabadi, M.; Lavold, T.; Zubarev, R. A. Separation of polypeptides by isoelectric point focusing in electrospray-friendly solution using multiple-junction capillary fractionator, Anal. Chem. 2012, 84, 6856-6862. http://www.ncbi.nlm.nih.gov/pubmed/22779778
  2. Pirmoradian, M.; Zhang, B.; Chingin, K.; Astorga-Wells, J.; Zubarev, R. A. Membrane-assisted isoelectric focusing device as a micro-preparative fractionator for two dimensional shotgun proteomics, Anal. Chem, 2014, 86, 5728-5732.
    http://pubs.acs.org/doi/abs/10.1021/ac404180e
  3. Pirmoradian, M.; Astorga-Wells, J.; Zubarev, R. A. Multijunction Capillary Isoelectric Focusing Device Combined with Online Membrane-Assisted Buffer Exchanger Enables Isoelectric Point Fractionation of Intact Human Plasma Proteins for Biomarker Discovery. Anal Chem 2015, 87, DOI: 10.1021/acs.analchem.5b03344.
    http://www.ncbi.nlm.nih.gov/pubmed/26531800

Further publications

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